Journal : Acta Chromatographica
Article : Bis(salicylaldehyde) orthophenylenediamine as complexing reagent in simultaneous determination of gold, chromium, iron, uranyl, and nickel using capillary zone electrophoresis

Authors :
Xu, L. N.
Yantai University Department of Applied Chemistry Yantai 264005 P.R. China,
Gai, F. Y.
Yantai University Department of Applied Chemistry Yantai 264005 P.R. China,
Mu, G. F.
Yantai University Department of Applied Chemistry Yantai 264005 P.R. China,
Gao, Y.
Yantai University Department of Applied Chemistry Yantai 264005 P.R. China,
Liu, C. J.
Yantai University Department of Applied Chemistry Yantai 264005 P.R. China,
Luan, F.
Yantai University Department of Applied Chemistry Yantai 264005 P.R. China,
Mori, M.
Gunma University Department of Chemistry and Chemical Biology, Graduate School of Engineering 1-5-1 Tenjin-cho Kiryu 376-8515 Japan,
Ikeda, T.
Gunma University Department of Chemistry and Chemical Biology, Graduate School of Engineering 1-5-1 Tenjin-cho Kiryu 376-8515 Japan,
Itabashi, H.
Gunma University Department of Chemistry and Chemical Biology, Graduate School of Engineering 1-5-1 Tenjin-cho Kiryu 376-8515 Japan,
Soomro, R.
University of Sindh National Center of Excellence in Analytical Chemistry Jamshoro Pakistan,
Memon, S. Q.
University of Sindh Institute of Advance Research in Chemical Sciences Jamshoro Pakistan,
Ahmed, M. J.
University of Chittagong Laboratory of Analytical Chemistry, Department of Chemistry Chittagong 4331 Bangladesh,
Memon, N.
University of Sindh National Center of Excellence in Analytical Chemistry Jamshoro Pakistan, najmamemon@gmail.com,
Mallah, A.
University of Sindh M.A. Kazi Institute of Chemistry Jamshoro Pakistan,
Abstract : Bis(salicylaldehyde) orthophenylenediamine (BSOPD) is reported here as a complexing reagent for simultaneous determination of six metal ions, gold, chromium, iron(II)/(III), uranyl, and nickel, by capillary zone electrophoresis. The pre-derivatized complexes were injected onto 50 cm bare silica capillary (i.d. 75 µm) with background electrolyte 50 mM citrate:oxalate buffer in 1:1 at pH 4. All metal ions were separated within 15 min including coexisted ions at applied voltage of −15 kV at detection wavelength of 250 nm. Under the abovementioned conditions, limits of quantification and detection were found to be 0.5, 1.0, 1.0, 10.0, 1.0, and 10.0 µg mL-1; and 0.16, 0.33, 0.33, 3.33, 0.33, and 3.33 µg mL-1for Au(III), Cr(VI), Fe(III), Fe(II), UO2(II), and Ni(II), respectively. Linear calibration graphs were obtained in the ranges of 0.5–100, 1–200, 10–100, 1–100, 1–100, and 10–200 µg mL-1with the correlation coefficient values 0.9964, 0.9948, 0.9900, 0.9999, 0.9992, and 0.9918 for Au(III); and Cr(VI), Fe(III), Fe(II), UO2(II), and Ni(II), respectively. Applicability of the method has been evaluated by determining gold from wastewater samples of goldsmith factories and uranyl from ore samples. The developed method was also used for the determination of chromium in selected environmental waters (drinking and polluted). The data obtained with developed method were compared with those obtained from atomic absorption spectroscopy, and the results of the analysis were found to be in good agreement.

Keywords : capillary zone electrophoresis, separation of gold, chromium, iron, uranyl and nickel, bis(salicylaldehyde) orthophenylenediamine,
Publishing house : University of Silesia in Katowice
Publication date : 2012
Number : Vol. 24, no. 4
Page : 543 – 558

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DOI :
Qute : Xu, L. N. ,Gai, F. Y. ,Mu, G. F. ,Gao, Y. ,Liu, C. J. ,Luan, F. ,Mori, M. ,Ikeda, T. ,Itabashi, H. ,Soomro, R. ,Memon, S. Q. ,Ahmed, M. J. ,Memon, N. ,Mallah, A. ,Mallah, A. , Bis(salicylaldehyde) orthophenylenediamine as complexing reagent in simultaneous determination of gold, chromium, iron, uranyl, and nickel using capillary zone electrophoresis. Acta Chromatographica Vol. 24, no. 4/2012
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