Comparative study of the kinetic approach on the alcoholic fermentation procedure conducted in laboratory and scale-up systems by inverse gas chromatography

Czasopismo : Acta Chromatographica
Tytuł artykułu : Comparative study of the kinetic approach on the alcoholic fermentation procedure conducted in laboratory and scale-up systems by inverse gas chromatography

Autorzy :
Mansoor, S.
Georgia Institute of Technology School of Chemical and Biomolecular Engineering Atlanta GA 30332-0100 USA,
Tas, C.
Georgia Institute of Technology School of Chemical and Biomolecular Engineering Atlanta GA 30332-0100 USA, ctas@gata.edu.tr,
Patel, D. S.
Pramukh Swami Science and H.D. Patel Arts College Chemistry Department Sarva Vidyalaya Campus Kadi 382 715 Gujarat India,
Sharma, N.
BA Research India Ltd. Bio-Analytical Laboratory Bodakdev, Ahmedabad 380054 Gujarat India,
Patel, M. C.
Pramukh Swami Science and H.D. Patel Arts College Chemistry Department Sarva Vidyalaya Campus Kadi 382 715 Gujarat India,
Patel, B. N.
BA Research India Ltd. Bio-Analytical Laboratory Bodakdev, Ahmedabad 380054 Gujarat India, bhavinpatel27@rediffmail.com,
Shrivastav, P. S.
Gujarat University Department of Chemistry, School of Sciences Navrangpura, Ahmedabad 380009 Gujarat India, pranav_shrivastav@yahoo.com,
Sanyal, M.
St. Xavier’s College Department of Chemistry Navrangpura, Ahmedabad 380009 Gujarat India,
Wang, G. Y.
Chinese Academy of Sciences Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics Lanzhou 730000 P. R. China,
Shi, Y. P.
Lanzhou University of Technology School of Petroleum and Chemical Engineering Lanzhou 730050 P. R. China, shiyp@licp.cas.cn,
Akowuah, G. A.
UCSI University Faculty of Applied Sciences No. 1, Jalan Menara Gading, UCSI Heights 56000 Kuala Lumpur Malaysia, wuahmy@yahoo.com,
Okechukwu, P. N.
UCSI University Faculty of Pharmaceutical Sciences No. 1, Jalan Menara Gading, UCSI Heights 56000 Kuala Lumpur Malaysia,
Chiam, N. C.
UCSI University Faculty of Pharmaceutical Sciences No. 1, Jalan Menara Gading, UCSI Heights 56000 Kuala Lumpur Malaysia,
Raszewski, G.
Institute of Agricultural Medicine Department of Pathophysiology Lublin Poland, grasz@galen.imw.lublin.pl,
Juszczak, M.
Institute of Agricultural Medicine Department of Medical Biology Lublin Poland,
Lemieszek, M. K.
Institute of Agricultural Medicine Department of Medical Biology Lublin Poland,
Matysiak, J.
University of Life Sciences Department of Chemistry Lublin Poland,
Niewiadomy, A.
University of Life Sciences Department of Chemistry Lublin Poland,
Rzeski, W.
Maria Curie-Sklodowska University Department of Virology and Immunology, Institute of Microbiology and Biotechnology Lublin Poland,
Reddy, P. S.
IPDO Dr. Reddy’s Laboratories Ltd. Bachupally, Hyderabad 500072 A.P India, sunilpsr@yahoo.com,
Babu, K. S.
S. K. University Department of Chemistry Anantapur 515055 A.P. India,
Kumar, N.
IPDO Dr. Reddy’s Laboratories Ltd. Bachupally, Hyderabad 500072 A.P India,
Pareek, D.
Rajiv Gandhi Technological University School of Pharmaceutical Sciences Bhopal 462033 Madhya Pradesh India,
Jain, S.
Sagar Institute of Research and Technology Ayodhya bypass, Bhopal 462 041 MP India,
Basniwa, P. K.
Rajiv Gandhi Technological University School of Pharmaceutical Sciences Bhopal 462033 Madhya Pradesh India,
Jain, D.
Rajiv Gandhi Technological University School of Pharmaceutical Sciences Bhopal 462033 Madhya Pradesh India, deepti2515@yahoo.com,
Wróblewski, K.
Medical University of Lublin Department of Inorganic Chemistry 4a Chodźki Str. 20-093 Lublin Poland,
Petruczynik, A.
Medical University of Lublin Department of Inorganic Chemistry 4a Chodźki Str. 20-093 Lublin Poland,
Waksmundzka-Hajnos, M.
Medical University of Lublin Department of Inorganic Chemistry 4a Chodźki Str. 20-093 Lublin Poland, monika.hajnos@umlub.pl,
Jain, P. S.
R. C. Patel Institute of Pharmaceutical Education and Research Karwand Naka, Shirpur, Dist. Dhule 425 405 MS India, pritash79@yahoo.com,
Chaudhari, A. J.
R. C. Patel Institute of Pharmaceutical Education and Research Karwand Naka, Shirpur, Dist. Dhule 425 405 MS India,
Surana, S. J.
R. C. Patel Institute of Pharmaceutical Education and Research Karwand Naka, Shirpur, Dist. Dhule 425 405 MS India,
Elgorashe, R. E. E.
Sudan University of Science and Technology Department of Chemistry, College of Science Khartoum Sudan,
Idris, A. M.
King Khalid University Department of Chemistry, College of Science Abha Saudi Arabia, abubakridris@hotmail.com,
Abdelrahman, M. A.
Sudan University of Science and Technology Department of Chemistry, College of Science Khartoum Sudan,
Saeed, A. E. M.
Sudan University of Science and Technology Department of Chemistry, College of Science Khartoum Sudan,
Gawlik, M.
Jagiellonian University Medical College Department of Toxicology, Faculty of Pharmacy Medyczna str. 9 30-688 Kraków Poland,
Krzyżanowska, W.
Jagiellonian University Medical College Department of Toxicology, Faculty of Pharmacy Medyczna str. 9 30-688 Kraków Poland,
Gawlik, M. B.
Jagiellonian University Medical College Department of Toxicology, Faculty of Pharmacy Medyczna str. 9 30-688 Kraków Poland, mfgawlik@cyf-kr.edu.pl,
Filip, M.
Jagiellonian University Medical College Department of Toxicology, Faculty of Pharmacy Medyczna str. 9 30-688 Kraków Poland,
Tomsej, T.
VŠB-Technical University of Ostrava Institute of Clean Technologies 17. listopadu 15 708 33 Ostrava-Poruba Czech Republic, ttomsej@email.cz,
Tomsejova, S.
National Reference Laboratory for POP Institute of Public Health Ostrava Partyzanske namesti 7 702 00 Ostrava Czech Republic,
Dombek, V.
VŠB-Technical University of Ostrava Institute of Clean Technologies 17. listopadu 15 708 33 Ostrava-Poruba Czech Republic,
Maciejowska, A.
University of Silesia Institute of Chemistry 9 Szkolna Street 40-006 Katowice Poland,
Godziek, A.
University of Silesia Institute of Chemistry 9 Szkolna Street 40-006 Katowice Poland,
Sajewicz, M.
University of Silesia Institute of Chemistry 9 Szkolna Street 40-006 Katowice Poland,
Kowalska, T.
University of Silesia Institute of Chemistry 9 Szkolna Street 40-006 Katowice Poland, teresa.kowalska@us.edu.pl,
Lainioti, G. C.
University of Patras Department of Chemistry GR-26504 Patras Greece,
Kapolos, J.
Technological Educational Institute of Kalamata Department of Food Technology 24100 Kalamata Greece,
Koliadima, A.
University of Patras Department of Chemistry GR-26504 Patras Greece,
Karaiskakis, G.
University of Patras Department of Chemistry GR-26504 Patras Greece, G.Karaiskakis@chemistry.upatras.gr,
Abstrakty : The major objective of the present work was to compare the kinetic study of alcoholic fermentations conducted in the presence of wheat supported biocatalysts in laboratory scale and in a scale-up system of 80 L and to compare these results with those reported in literature. The kinetic study of fermentation processes was accomplished with the technique of reversed flow gas chromatography (RFGC), which is a version of inverse gas chromatography. The wine yeast species used was Saccharomyces cerevisiae AXAZ-1, and fermentations were conducted between 20 and 2°C. At low temperatures, maximal ethanol productivity and fermentation rate were reduced. The rate constants, determined through a mathematical model obtained from RFGC, were higher in the laboratory scale comparing to the scale-up system at the temperatures of 20 and 15°C. However, with the reduction of temperature, both systems presented almost similar values proving the great fermentative ability of immobilized cells even at extremely low temperatures. Activation energies of the alcoholic fermentations in the two systems presented their higher values at the second phase (stationary) compared to those observed at the other two phases (growth and decline).

Słowa kluczowe : alcoholic fermentation, immobilization carrier, rate constants, reverse flow gas chromatography, scale-up process,
Wydawnictwo : University of Silesia in Katowice
Rocznik : 2014
Numer : Vol. 26, no. 2
Strony : 371 – 389
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DOI :
Cytuj : Mansoor, S. ,Tas, C. ,Patel, D. S. ,Sharma, N. ,Patel, M. C. ,Patel, B. N. ,Shrivastav, P. S. ,Sanyal, M. ,Wang, G. Y. ,Shi, Y. P. ,Akowuah, G. A. ,Okechukwu, P. N. ,Chiam, N. C. ,Raszewski, G. ,Juszczak, M. ,Lemieszek, M. K. ,Matysiak, J. ,Niewiadomy, A. ,Rzeski, W. ,Reddy, P. S. ,Babu, K. S. ,Kumar, N. ,Pareek, D. ,Jain, S. ,Basniwa, P. K. ,Jain, D. ,Wróblewski, K. ,Petruczynik, A. ,Waksmundzka-Hajnos, M. ,Jain, P. S. ,Chaudhari, A. J. ,Surana, S. J. ,Elgorashe, R. E. E. ,Idris, A. M. ,Abdelrahman, M. A. ,Saeed, A. E. M. ,Gawlik, M. ,Krzyżanowska, W. ,Gawlik, M. B. ,Filip, M. ,Tomsej, T. ,Tomsejova, S. ,Dombek, V. ,Maciejowska, A. ,Godziek, A. ,Sajewicz, M. ,Kowalska, T. ,Lainioti, G. C. ,Kapolos, J. ,Koliadima, A. ,Karaiskakis, G. , Comparative study of the kinetic approach on the alcoholic fermentation procedure conducted in laboratory and scale-up systems by inverse gas chromatography. Acta Chromatographica Vol. 26, no. 2/2014
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