Journal : Acta Chromatographica
Article : Comparison of headspace solvent microextraction, hydrodistillation solvent microextraction, and solid-phase microextraction for the study of volatile components of Kelussia odoratissima Mozaff. by GC-MS

Authors :
Sajewicz, M.
University of Silesia Institute of Chemistry 9 Szkolna Street 40-006 Katowice Poland,
Gontarska, M.
University of Silesia Institute of Chemistry 9 Szkolna Street 40-006 Katowice Poland,
Kronenbach, D.
University of Silesia Institute of Chemistry 9 Szkolna Street 40-006 Katowice Poland,
Berry, E.
University of Silesia Institute of Chemistry 9 Szkolna Street 40-006 Katowice Poland,
Kowalska, T.
University of Silesia Institute of Chemistry 9 Szkolna Street 40-006 Katowice Poland, teresa.kowalska@us.edu.pl,
Deshpande, P. B.
A.I.S.S.M.S. College of Pharmacy Department of Pharmaceutical Analysis Kennedy Road Pune 411001 MH India, padmanabh77@yahoo.co.in,
Gandhi, S. V.
A.I.S.S.M.S. College of Pharmacy Department of Pharmaceutical Analysis Kennedy Road Pune 411001 MH India,
Gaikwad, N. V.
A.I.S.S.M.S. College of Pharmacy Department of Pharmaceutical Analysis Kennedy Road Pune 411001 MH India,
Khandagle, K. S.
A.I.S.S.M.S. College of Pharmacy Department of Pharmaceutical Analysis Kennedy Road Pune 411001 MH India,
Sateesh, J. N.
PRRM College of Pharmacy Department of Chemistry Kadapa Andhra Pradesh India, nagasateesh@gmail.com,
Subba Reedy, G. V.
JNTUA College of Engineering Department of Chemistry Pulivendula, Y.S.R (Kadapa) Andhra Pradesh India,
Jayaveera, K. N.
awaharlal Nehru Technological University Anantapur Oil Technology Research Institute Anantapur Andhra Pradesh India,
Dhayalamurthi, S.
Mother Theresa Post Graduate & Research Institute of Health Sciences Department of Chemistry, College of Pharmacy Gorimedu Puducherry India,
Anandakumar, K.
Adhiparasakthi College of Pharmacy Department of Pharmaceutical Analysis Melmaruvathur 603 319 Tamil Nadu India, anandkarunakaran@gmail.com,
Jothieswari, D.
Adhiparasakthi College of Pharmacy Department of Pharmaceutical Analysis Melmaruvathur 603 319 Tamil Nadu India,
Subathrai, R.
Adhiparasakthi College of Pharmacy Department of Pharmaceutical Analysis Melmaruvathur 603 319 Tamil Nadu India,
Santhi, D. V.
Adhiparasakthi College of Pharmacy Department of Pharmaceutical Analysis Melmaruvathur 603 319 Tamil Nadu India,
Vetrichelvan, T.
Adhiparasakthi College of Pharmacy Department of Pharmaceutical Analysis Melmaruvathur 603 319 Tamil Nadu India,
Shah, D. A.
Indukaka Ipcowala College of Pharmacy P.B. No. 53 New Vallabh Vidyanagar 388 121 Dist. Anand Gujarat India, dimalgroup@yahoo.com,
Bhatt, K. K.
Indukaka Ipcowala College of Pharmacy P.B. No. 53 New Vallabh Vidyanagar 388 121 Dist. Anand Gujarat India,
Baldania, S. L.
Indukaka Ipcowala College of Pharmacy P.B. No. 53 New Vallabh Vidyanagar 388 121 Dist. Anand Gujarat India,
Tian, M.
Inha University Department of Chemical Engineering 253 Yonghyun-Dong, Nam-Ku Incheon 402-751 Korea,
Li, S.
Inha University Department of Chemical Engineering 253 Yonghyun-Dong, Nam-Ku Incheon 402-751 Korea,
Row, K. H.
Inha University Department of Chemical Engineering 253 Yonghyun-Dong, Nam-Ku Incheon 402-751 Korea, rowkho@inha.ac.kr,
Azar, P. A.
Islamic Azad University, Science and Research Branch Department of Chemistry P.O. Box 14155/4933 Tehran Iran, pabroomand@yahoo.com,
Porgham-Daryasari, A.
Islamic Azad University, Science and Research Branch Department of Chemistry P.O. Box 14155/4933 Tehran Iran,
Saber-Tehrani, M.
Islamic Azad University, Science and Research Branch Department of Chemistry P.O. Box 14155/4933 Tehran Iran,
Soleimani, M.
Islamic Azad University, Lahijan Branch Department of Chemistry, Faculty of Science P.O. Box 1616 Lahijan Iran,
Patel, M. B.
Atmiya Institute of Pharmacy Department of Pharmacognosy and Phytochemistry Yogidham Gurukul, Kalawad Road Rajkot Gujarat India, mayur.pharma@gmail.com,
Mishra, S. H.
The M.S. University of Baroda Pharmacy Department, Faculty of Technology and Engineering, Kalabhavan Vadodara 390 001 Gujarat India,
Hashemi, P.
Lorestan University Department of Chemistry, Faculty of Science Khoramabad Iran, payman_hashemi@yahoo.com,
Yarahmadi, A.
Lorestan University Department of Chemistry, Faculty of Science Khoramabad Iran,
Shamizadeh, M.
Lorestan University Department of Chemistry, Faculty of Science Khoramabad Iran,
Khademi, K.
Agriculture and Natural Resource Research Center P.O. Box 348 Khoramabad Iran,
Abstract : Kelussia odoratissima Mozaff. is a wild and endangered endemic plant found only in limited areas of central Zagros mountains, Iran. Three microextraction methods, that is, headspace solvent microextraction (HS-SME), hydrodistillation solvent microextraction (HD-SME), and solid-phase microextraction (SPME), and a conventional hydrodistillation method were used and compared for the extraction and gas chromatography- mass spectrometric (GC-MS) analysis of volatile components of the plant. In the HS-SME and HD-SME methods, a suspended n-heptadecane microdroplet was used for the extraction from the sample headspace, while in the SPME method, a PDMS fiber was applied. The highest extraction efficiency was obtained for the SPME method, with the highest number of identified components and best precision. As a consequence, the SPME method was used for the comparison of the volatile components of seeds, leaves, and pedicles of K. odoratissima collected from three different regions. One of the major components of the plant was butyl phthalide. The levels of this compound in the extractions from leaves, pedicles, and seeds were 34.1, 23.8, and 12.9%, respectively. The results also showed considerable variation between the volatile components of the samples collected from different areas.

Keywords : Kelussia odoratissima Mozaff, aerial parts, hydrodistillation solvent microextraction, headspace solvent microextraction, gas chromatography-mass spectrometry,
Publishing house : University of Silesia in Katowice
Publication date : 2012
Number : Vol. 24, no. 1
Page : 97 – 109

Bibliography
: 1 Z. Zhang and J. Pawliszyn, Anal. Chem., 65, 1843 (1993)
2 P. Hashemi, M. Shamizadeh, A. Badiei, A.R. Ghiasvand, and K. Azizi, Chromatographia, 70, 1147 (2009)
3 P. Hashemi, A. Yarahmadi, K. Azizi, and B. Sabouri, Chromatographia, 67, 253 (2008)
4 L. Xu, C. Basheer, and H.K. Lee, J. Chromatogr. A, 1152, 184 (2007)
5 F. Rezaei, A. Bidari, A.P. Birjandi, M.R.M. Hosseini, and Y. Assadi, J. Hazard. Mater., 158, 621 (2008)
6 P. Hashemi, S. Beyranvand, R. Siah Mansur, and A.R. Ghiasvand, Anal. Chim. Acta, 655, 60 (2009)
7 P. Hashemi, M.M. Abolghasemi, A.R. Ghiasvand, S. Ahmadi, H. Hassanvand, and A. Yarahmadi, Chromatographia, 69, 179 (2009)
8 P. Hashemi, M.M. Abolghasemi, A.R. Fakhari, S.N. Ebrahimi, and S. Ahmadi, Chromatographia, 66, 283 (2007)
9 R. Omidbaigi, F. Sefidkon, and K. Saeedi, JEOBP, 11, 594 (2008)
10 F. Ahmadi, M. Kadivar, and M. Shahedi, Food Chem., 105, 57 (2007)
11 K. Saeedi and R. Omidbaigi, Iran. J. Med. Arom. Plants, 25, 113 (2009)
12 R.P. Adams, Identification of Essential Oil Components by Gas Chromatography/Mass Spectroscopy, Allured Publishing Corporation, Carol Stream, IL, 2007
13 R.G. Brereton, Chemometrics: Data Analysis for the Laboratory and Chemical Plant, John Wiley & Sons Ltd, West Sussex, England, 2003
14 M. Borzoei, M Sc. thesis, Department of Chemistry, Lorestan University, Khoramabad, Iran, 2008
15 G. MacLeod and J.M. Ames, Phytochemistry, 28, 1817 (1989)
16 P. Hashemi, B. Delfan, A.R. Ghiasvand, M. Alborzi, and F. Raeisi, Acta Chromatogr., 22, 131 (2010)
DOI :
Qute : Sajewicz, M. ,Gontarska, M. ,Kronenbach, D. ,Berry, E. ,Kowalska, T. ,Deshpande, P. B. ,Gandhi, S. V. ,Gaikwad, N. V. ,Khandagle, K. S. ,Sateesh, J. N. ,Subba Reedy, G. V. ,Jayaveera, K. N. ,Dhayalamurthi, S. ,Anandakumar, K. ,Jothieswari, D. ,Subathrai, R. ,Santhi, D. V. ,Vetrichelvan, T. ,Shah, D. A. ,Bhatt, K. K. ,Baldania, S. L. ,Tian, M. ,Li, S. ,Row, K. H. ,Azar, P. A. ,Porgham-Daryasari, A. ,Saber-Tehrani, M. ,Soleimani, M. ,Patel, M. B. ,Mishra, S. H. ,Hashemi, P. ,Yarahmadi, A. ,Shamizadeh, M. ,Khademi, K. ,Khademi, K. , Comparison of headspace solvent microextraction, hydrodistillation solvent microextraction, and solid-phase microextraction for the study of volatile components of Kelussia odoratissima Mozaff. by GC-MS. Acta Chromatographica Vol. 24, no. 1/2012
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