Determination of selected PAH carbonyl derivatives by TLC with densitometric detection

Czasopismo : Acta Chromatographica
Tytuł artykułu : Determination of selected PAH carbonyl derivatives by TLC with densitometric detection

Autorzy :
Kowalska, T.
Institute of Chemistry, Silesian University, 9 Szkolna Street, 40-006 Katowice, Poland,
Kaczmarski, K.
Chemical Engineering Department, Rzeszów University of Technology, Rzeszów, Poland,
Pavlova, A.
Analytical Department, Research and Development Institute, Lukoil-Neftochim-Bourgas-AD, 8104 Bourgas, Bulgaria,
Giza, I.
Plant Protection Institute, Sośnicowice Branch, ul. Gliwicka 29, 44-153 Sośnicowice, Poland,
Walorczyk, S.
Institute of Plant Protection, Department of Pesticide Residue Research, ul. Miczurina 20, 60-318 Poznań, Poland,
Waksmundzka-Hajnos, M.
Department of Inorganic and Analytical Chemistry, Medical University, Staszica 6, 20-081 Lublin, Poland,
Gadzikowska, M.
Department of Inorganic and Analytical Chemistry, Medical Academy, Staszica 6, 20-081 Lublin, Poland,
Nagahashi, M.
Laboratory of Instrumental Analysis, Tokyo University of Agriculture, 1-1, Sakuragaoka-1, Setagaya, Tokyo 156-8502, Japan,
Fisher, J.
Department of Chemistry, Lafayette College, Easton, PA 18042, USA,
Schariter, J. J.
Department of Chemistry, Lafayette College, Easton, PA 18042, USA,
Bodzek, D.
Department of Chemistry, Faculty of Medicine, Medical University of Silesia, 41-808 Zabrze, Jordana 19, Poland,
Abstrakty : Thin layer chromatography on aluminium-backed silica gel and C18 plates, with dichloromethane and a mixture of methanol, water, and acetonitrile, respectively, as mobile phases, has been used to develop methods for separation, identification, and quantification of the polyaromatic carbonyl compounds most commonly found in environmental samples. Chromatograms were developed in a horizontal chamber and compounds were quantified by means of a Shimadzu CS-9301 densitometer. RF values and detection limits for both chromatographic systems were measured for ten polyaromatic carbonyl compounds. Selective separation was achieved by normal phase chromatography on silica gel 60F254 with dichloromethane as mobile phase. The determination limits for the compounds studied were within the range 10-40 ng per spot.

Słowa kluczowe :
Wydawnictwo : University of Silesia in Katowice
Rocznik : 2001
Numer : No. 11
Strony : 108 – 117
Bibliografia :
DOI :
Cytuj : Kowalska, T. ,Kaczmarski, K. ,Pavlova, A. ,Giza, I. ,Walorczyk, S. ,Waksmundzka-Hajnos, M. ,Gadzikowska, M. ,Nagahashi, M. ,Fisher, J. ,Schariter, J. J. ,Bodzek, D. , Determination of selected PAH carbonyl derivatives by TLC with densitometric detection. Acta Chromatographica No. 11/2001
facebook