Development and validation of an ultrasound-assisted surfactant-enhanced emulsification microextraction method for liquid chromatographic determination of carbamate residues in fruit juices

Czasopismo : Acta Chromatographica
Tytuł artykułu : Development and validation of an ultrasound-assisted surfactant-enhanced emulsification microextraction method for liquid chromatographic determination of carbamate residues in fruit juices

Autorzy :
Gwarda, R. Ł.
Medical University of Lublin Department of Physical Chemistry, Chair of Chemistry 4a Chodźki Street 20-093 Lublin Poland, radoslaw.gwarda@umlub.pl,,
Tomczyszyn, A.
University of Warsaw Faculty of Chemistry 1 Pasteura Street 02-093 Warsaw Poland,
Misicka, A.
University of Warsaw Faculty of Chemistry 1 Pasteura Street 02-093 Warsaw Poland,
Dzido, T. H.
Medical University of Lublin Department of Physical Chemistry, Chair of Chemistry 4a Chodźki Street 20-093 Lublin Poland,
Xue, X. D.
Yunnan Normal University Department of Chemistry Kunming 650092 P.R. China,
Zhang, M.
East China Normal University Department of Chemistry Shanghai 200241 P.R. China,
Xie, S. M.
Yunnan Normal University Department of Chemistry Kunming 650092 P.R. China,
Yuan, L. M.
Yunnan Normal University Department of Chemistry Kunming 650092 P.R. China, yuan_limingpd@yahoo.com.cn,
Matta, M. K.
Jawaharlal Nehru Technological University University College of Pharmaceutical Sciences Hyderabad 500 085 India,
Pilli, N. R.
Jawaharlal Nehru Technological University University College of Pharmaceutical Sciences Hyderabad 500 085 India,
Rao, J. V. L. N. S.
Yalamarty College of Pharmaceutical Sciences Visakhapatnam 530 052 India, jvlnsrao@rediffmail.com,
Abdelhay, M. H.
University of Alexandria Pharmaceutical Analytical Chemistry Department, Faculty of Pharmacy Elmessalah, Alexandria 21521 Egypt,
Gazy, A. A.
University of Alexandria Pharmaceutical Analytical Chemistry Department, Faculty of Pharmacy Elmessalah, Alexandria 21521 Egypt,
Shaalan, R. A.
rasha_shaalan@yahoo.com,
Ashour, H. K.
University of Alexandria Pharmaceutical Analytical Chemistry Department, Faculty of Pharmacy Elmessalah, Alexandria 21521 Egypt,
Krasucka, D.
National Veterinary Research Institute — National Research Institute Department of Veterinary Pharmacy Al. Partyzantów 57 24-100 Pulawy Poland,
Kowalski, C. J.
University of Life Sciences in Lublin Department of Pharmacology, Faculty of Veterinary Medicine Akademicka 12 20-033 Lublin Poland,
Osypiuk, M.
University of Life Sciences in Lublin Department of Pharmacology, Faculty of Veterinary Medicine Akademicka 12 20-033 Lublin Poland, monika.osypiuk@up.lublin.pl,
Opielak, G.
Medical University School of Lublin Human Anatomy Department Jaczewskiego 4 20-090 Lublin Poland,
Mahgoub, H.
King Abdulaziz University Department of Pharmaceutical Chemistry, Faculty of Pharmacy Jeddah Saudi Arabia, hodamahgoub@yahoo.com,
Hanafy, A.
King Abdulaziz University Department of Pharmacology and Toxicology, Faculty of Pharmacy Jeddah Saudi Arabia,
Bamane, F. H.
King Abdulaziz University Department of Biochemistry, Faculty of Medicine Jeddah Saudi Arabia,
Radwan, A. E.
University of Alexandria Department of Biotechnology, Institute of Graduate Studies and Research Alexandria Egypt,
Wen, C.
Wenzhou Medical College Laboratory Animal Centre Wenzhou 325035 China,
Zhang, Q.
Shanghai Institute of Pharmaceutical Industry Shanghai 200437 China,
He, Y.
Wenzhou Medical College Laboratory Animal Centre Wenzhou 325035 China,
Deng, M.
Wenzhou Medical College Laboratory Animal Centre Wenzhou 325035 China,
Wang, X.
Wenzhou Medical College Laboratory Animal Centre Wenzhou 325035 China,
Ma, J.
Wenzhou Medical College Function Experiment Teaching Center Wenzhou 325035 China, jianshema@gmail.com,
Wang, Y.
National Institutes for Food and Drug control (NIFDC) Beijing 100050 P.R. China,
Wang, M. J.
National Institutes for Food and Drug control (NIFDC) Beijing 100050 P.R. China,
Li, J.
National Institutes for Food and Drug control (NIFDC) Beijing 100050 P.R. China,
Yao, S. C.
National Institutes for Food and Drug control (NIFDC) Beijing 100050 P.R. China,
Xue, J.
National Institutes for Food and Drug control (NIFDC) Beijing 100050 P.R. China,
Zou, W. B.
National Institutes for Food and Drug control (NIFDC) Beijing 100050 P.R. China,
Hu, C.
National Institutes for Food and Drug control (NIFDC) Beijing 100050 P.R. China, hucq@nicpbp.org.cn,
Idris, A. M.
King Khalid University Department of Chemistry, College of Science Abha Saudi Arabia, abubakridris@hotmail.com,
Alnajjar, A. O.
King Faisal University Department of Chemistry, College of Science Hofuf Saudi Arabia,
Vichapong, J.
Khon Kaen University Materials Chemistry Research Unit, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science Khon Kaen 40002 Thailand,
Burakham, R.
Khon Kaen University Materials Chemistry Research Unit, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science Khon Kaen 40002 Thailand, rodjbu@kku.ac.th,
Abstrakty : A microextraction procedure based on ultrasound-assisted surfactant-enhanced emulsification microextraction (UASEME) was optimized and validated for preconcentration of carbamate pesticides prior to fast determination using high-performance liquid chromatography (HPLC) with monolithic column. The nonionic surfactant (Tween 20) was used as an emulsifier, and chloroform was selected as an extraction solvent. The experimental parameters affecting the extraction efficiency, such as the kind, concentration, and volume of surfactant, the kind of extraction solvent and its volume, salt addition, ultrasonic extraction time, and centrifugation time, were optimized. Under the selected UASEME and HPLC conditions, separation of five carbamate pesticides (carbofuran, carbaryl, isoprocarb, methiocarb, and promecarb) was achieved within 10 min. The linearity of the method was obtained in the wide range of 2–5000 μg L-1, with correlation coefficients of 0.9931–0.9970. The limits of detection were in the range of 0.4–7.0 μg L-1. The relative standard deviations (n = 5) were less than 0.59% and 4.86% for retention time and peak area, respectively. The enrichment factors of the developed UASEME method were in the range of 33–166. The fruit juice samples (at fortified levels of 0.25, 0.50, and 1.00 mg L-1) were successfully analyzed, and the relative recoveries were obtained in the range of 81–115%.

Słowa kluczowe : ultrasound-assisted surfactant-enhanced emulsification microextraction, HPLC, monolithic column, carbamates, fruit juice,
Wydawnictwo : University of Silesia in Katowice
Rocznik : 2015
Numer : Vol. 27, no. 1
Strony : 127 – 145
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DOI :
Cytuj : Gwarda, R. Ł. ,Tomczyszyn, A. ,Misicka, A. ,Dzido, T. H. ,Xue, X. D. ,Zhang, M. ,Xie, S. M. ,Yuan, L. M. ,Matta, M. K. ,Pilli, N. R. ,Rao, J. V. L. N. S. ,Abdelhay, M. H. ,Gazy, A. A. ,Shaalan, R. A. ,Ashour, H. K. ,Krasucka, D. ,Kowalski, C. J. ,Osypiuk, M. ,Opielak, G. ,Mahgoub, H. ,Hanafy, A. ,Bamane, F. H. ,Radwan, A. E. ,Wen, C. ,Zhang, Q. ,He, Y. ,Deng, M. ,Wang, X. ,Ma, J. ,Wang, Y. ,Wang, M. J. ,Li, J. ,Yao, S. C. ,Xue, J. ,Zou, W. B. ,Hu, C. ,Idris, A. M. ,Alnajjar, A. O. ,Vichapong, J. ,Burakham, R. , Development and validation of an ultrasound-assisted surfactant-enhanced emulsification microextraction method for liquid chromatographic determination of carbamate residues in fruit juices. Acta Chromatographica Vol. 27, no. 1/2015
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