Journal : Acta Chromatographica
Article : Development of HPLC fingerprint for the quality control of Euonymus fortunei and distinguishing it from related species

Authors :
Sajewicz, M.
University of Silesia Department of General Chemistry and Chromatography 9 Szkolna Street 40-006 Katowice Poland,
Kowalska, T.
University of Silesia Department of General Chemistry and Chromatography 9 Szkolna Street 40-006 Katowice Poland, teresa.kowalska@us.edu.pl,
Szalka, M.
ICN Polfa Rzeszów S.A. Product Development Department 35-959 Rzeszów Poland,
Kostka, J.
Rzeszów University of Technology Department of Chemical and Process Engineering 35-959 Rzeszów,
Rokaszewski, E.
ICN Polfa Rzeszów S.A. Product Development Department 35-959 Rzeszów Poland,
Kaczmarski, K.
Rzeszów University of Technology Department of Chemical and Process Engineering 35-959 Rzeszów, kkaczmarski@prz.edu.pl,
Belal, F.
University of Mansoura Department of Analytical Chemistry, Faculty of Pharmacy 35516 Mansoura Egypt,
El-Brashy, A. M.
University of Mansoura Department of Analytical Chemistry, Faculty of Pharmacy 35516 Mansoura Egypt,
El-Enany, N.
University of Mansoura Department of Analytical Chemistry, Faculty of Pharmacy 35516 Mansoura Egypt,
Tolba, M. M.
University of Mansoura Department of Analytical Chemistry, Faculty of Pharmacy 35516 Mansoura Egypt,
Cielecka-Piontek, J.
Poznan University of Medical Sciences Department of Pharmaceutical Chemistry, Faculty of Pharmacy Grunwaldzka 6 60-780 Poznań Poland, jpiontek@ump.edu.pl,
Krause, A.
PozLab Contract Research Organization Poznań Poland,
Zalewski, P.
Poznan University of Medical Sciences Department of Pharmaceutical Chemistry, Faculty of Pharmacy Grunwaldzka 6 60-780 Poznań Poland,
Lunzer, A.
Tanaka Laboratory in Hokkaido University W 7, Kita-ku Sapporo 060-8638 Japan,
Jelińska, A.
Poznan University of Medical Sciences Department of Pharmaceutical Chemistry, Faculty of Pharmacy Grunwaldzka 6 60-780 Poznań Poland,
Sarju, N.
Universiti Teknologi Malaysia Department of Industrial Biotechnology, Faculty of Biosciences and Bioengineering 81310 Skudai, Johor Bahru, Johor Malaysia,
Abd Samad, A.
Universiti Teknologi Malaysia Department of Industrial Biotechnology, Faculty of Biosciences and Bioengineering 81310 Skudai, Johor Bahru, Johor Malaysia,
Abd Ghani, M.
Universiti Kebangsaan Malaysia School of Chemical Sciences and Food Technology 43600 UKM Bangi, Selangor Malaysia,
Ahmad, F.
Universiti Teknologi Malaysia Department of Chemistry, Faculty of Science 81310 Skudai, Johor Bahru, Johor Malaysia, farediah@kimia.fs.utm.my,
Yang, G. J.
China Pharmaceutical University School of Pharmacy Nanjing 210009 P. R. China, yanggongjun888@163.com,
Lv, L.
Yangzhou University College of Chemistry and Chemical Engineering Yangzhou 225002 P. R. China,
O’sullivan, C.
Lafayette College Department of Chemistry Easton PA 18042 USA,
Sherma, J.
Lafayette College Department of Chemistry Easton PA 18042 USA, shermaj@lafayette.edu,
Nagaraju, P. M.
Forensic Science Laboratory Madivala, Bangalore 560068 Karnataka India,
Sanganalmath, P. U.
Forensic Science Laboratory Madivala, Bangalore 560068 Karnataka India,
Kemparaju, K.
Mysore University Department of Studies in Biochemistry, Manasa Gangothri Mysore Karnataka India,
Mohan, B. M.
Forensic Science Laboratory Madivala, Bangalore 560068 Karnataka India, praveen_usp@yahoo.com,
Kumbhalkar, B. B.
Agharkar Research Institute Botany Group, Plant Science Division G.G. Agarkar Road Pune 411 004 India,
Rajopadhye, A. A.
Agharkar Research Institute Botany Group, Plant Science Division G.G. Agarkar Road Pune 411 004 India,
Upadhye, A. S.
Agharkar Research Institute Botany Group, Plant Science Division G.G. Agarkar Road Pune 411 004 India, upadhye.anuradha@gmail.com,
Hawrył, A.
Medical University of Lublin Departments of Inorganic Chemistry and Organic Chemistry Chodźki 4a 20-093 Lublin Poland,
Kuśmierz, E.
Medical University of Lublin Departments of Inorganic Chemistry and Organic Chemistry Chodźki 4a 20-093 Lublin Poland,
Pisarczyk, P.
Medical University of Lublin Departments of Inorganic Chemistry and Organic Chemistry Chodźki 4a 20-093 Lublin Poland,
Wujec, M.
Medical University of Lublin Departments of Inorganic Chemistry and Organic Chemistry Chodźki 4a 20-093 Lublin Poland,
Waksmundzka-Hajnos, M.
Medical University of Lublin Departments of Inorganic Chemistry and Organic Chemistry Chodźki 4a 20-093 Lublin Poland, monika.hajnos@am.lublin.pl,
Migas, P.
Medical University of Gdańsk Department of Pharmacognosy with the Medicinal Plants Garden Gen. J. Haller Al. 107 80-416 Gdańsk Poland, pmig@gumed.edu.pl,
Borys, I.
Medical University of Gdańsk Department of Pharmacognosy with the Medicinal Plants Garden Gen. J. Haller Al. 107 80-416 Gdańsk Poland,
Ouyang, X. L.
School of Chemistry & Chemical Engineering of Guangxi Normal University The Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources Guilin 541004 PR China,
Fang, X. M.
Guangxi Traditional Chinese Medical University Nanning 530001 PR China,
Pan, Y. M.
School of Chemistry & Chemical Engineering of Guangxi Normal University The Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources Guilin 541004 PR China,
Wei, L. X.
School of Chemistry & Chemical Engineering of Guangxi Normal University The Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources Guilin 541004 PR China,
Wang, H. S.
School of Chemistry & Chemical Engineering of Guangxi Normal University The Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources Guilin 541004 PR China, wang_hengshan@yahoo.com.cn,
Abstract : To control the quality of Euonymus fortunei (Turcz.) Hand.-Mazz., a simple and reliable method of high-performance liquid chromatography (HPLC) coupled with photodiode array detector (PAD) was developed for both fingerprint analysis and quantitative determination. Four representative flavonoids, namely, kaempferol-3-O-β-D-glucopyranosyl-(1→4)-α-L-rhamnopyranosyl-7-O-β-D-glucopyranosyl-(1→4)-α-L-rhamnopyranoside (I), kaempferol-3,7-O-α-dirhamnopyranoside (II), apigenin-7-O-β-D-glucopyranoside (III), and kaempferol-3-(4″-O-acetyl)-O-α-L-rhamnopyranoside-7-O-α-L-r hamnopyranoside (IV) isolated from E. fortunei, were used as reference compounds and simultaneously determined by the validated HPLC method. The unique properties of the chromatographic fingerprint were validated by analyzing 11 batches of E. fortunei, E. japonicus, E. laxiflorus, E. myrianthus, and E. hamiltonianus samples. Our results revealed that the chromatographic fingerprint combined with similarity measurement could efficiently identify and distinguish E. fortunei from the other investigated Euonymus species.

Keywords : Euonymus fortunei, HPLC, flavonoids, quality control, fingerprint analysis,
Publishing house : University of Silesia in Katowice
Publication date : 2012
Number : Vol. 24, no. 2
Page : 301 – 316

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DOI :
Qute : Sajewicz, M. ,Kowalska, T. ,Szalka, M. ,Kostka, J. ,Rokaszewski, E. ,Kaczmarski, K. ,Belal, F. ,El-Brashy, A. M. ,El-Enany, N. ,Tolba, M. M. ,Cielecka-Piontek, J. ,Krause, A. ,Zalewski, P. ,Lunzer, A. ,Jelińska, A. ,Sarju, N. ,Abd Samad, A. ,Abd Ghani, M. ,Ahmad, F. ,Yang, G. J. ,Lv, L. ,O’sullivan, C. ,Sherma, J. ,Nagaraju, P. M. ,Sanganalmath, P. U. ,Kemparaju, K. ,Mohan, B. M. ,Kumbhalkar, B. B. ,Rajopadhye, A. A. ,Upadhye, A. S. ,Hawrył, A. ,Kuśmierz, E. ,Pisarczyk, P. ,Wujec, M. ,Waksmundzka-Hajnos, M. ,Migas, P. ,Borys, I. ,Ouyang, X. L. ,Fang, X. M. ,Pan, Y. M. ,Wei, L. X. ,Wang, H. S. ,Wang, H. S. , Development of HPLC fingerprint for the quality control of Euonymus fortunei and distinguishing it from related species. Acta Chromatographica Vol. 24, no. 2/2012
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