Multidimensional TLC procedure for separation of complex natural mixtures spanning a wide polarity range; Application for fingerprint construction and for investigation of systematic relationships within the Peucedanum genus

Czasopismo : Acta Chromatographica
Tytuł artykułu : Multidimensional TLC procedure for separation of complex natural mixtures spanning a wide polarity range; Application for fingerprint construction and for investigation of systematic relationships within the Peucedanum genus

Autorzy :
Daszykowski, M.
Silesian University Department of Chemometrics, Institute of Chemistry 9 Szkolna Street 40-006 Katowice Poland,
Sajewicz, M.
Silesian University Department of General Chemistry and Chromatography 9 Szkolna Street 40-006 Katowice Poland,
Rzepa, J.
Silesian University Department of General Chemistry and Chromatography 9 Szkolna Street 40-006 Katowice Poland,
Hajnos, M.
Medical University of Lublin Department of Pharmacognosy 1 Chodźki Street 20-093 Lublin Poland,
Staszek, D.
Silesian University Department of General Chemistry and Chromatography 9 Szkolna Street 40-006 Katowice Poland,
Wojtal, Ł.
Silesian University Department of General Chemistry and Chromatography 9 Szkolna Street 40-006 Katowice Poland,
Kowalska, T.
Silesian University Department of General Chemistry and Chromatography 9 Szkolna Street 40-006 Katowice Poland,
Waksmundzka-Hajnos, M.
Medical University of Lublin Department of Inorganic Chemistry 6 Staszica Street 20-081 Lublin Poland,
Walczak, B.
Silesian University Department of Chemometrics, Institute of Chemistry 9 Szkolna Street 40-006 Katowice Poland, beata@us.edu.pl,
Skalicka-Woźniak, K.
Medical University of Lublin Department of Pharmacognosy with Medicinal Plant Laboratory 1 Chodzki Str. 20-093 Lublin Poland,
Markowski, W.
Medical University of Lublin Department of Physical Chemistry Staszica 6 20-081 Lublin Poland,
Świeboda, R.
Medical University of Lublin Department of Inorganic and Analytical Chemistry Staszica 6 20-081 Lublin Poland,
Głowniak, K.
Medical University of Lublin Department of Pharmacognosy with Medicinal Plant Laboratory 1 Chodzki Str. 20-093 Lublin Poland,
Sultana, N.
University of Karachi Research Institute of Pharmaceutical Sciences, Department of Pharmaceutical Chemistry, Faculty of Pharmacy Karachi 75270 Pakistan,
Arayne, M. S.
University of Karachi Department of Chemistry Karachi 75270 Pakistan,
Naveed, S.
University of Karachi Research Institute of Pharmaceutical Sciences, Department of Pharmaceutical Chemistry, Faculty of Pharmacy Karachi 75270 Pakistan,
Shamshad, H.
University of Karachi Research Institute of Pharmaceutical Sciences, Department of Pharmaceutical Chemistry, Faculty of Pharmacy Karachi 75270 Pakistan,
Li, X.
China Agricultural University Department of Applied Chemistry, College of Science Beijing 100193 China,
Xu, J.
China Agricultural University Department of Applied Chemistry, College of Science Beijing 100193 China,
Jiang, Y.
China Agricultural University Department of Applied Chemistry, College of Science Beijing 100193 China,
Chen, L.
China Agricultural University Department of Applied Chemistry, College of Science Beijing 100193 China,
Xu, Y.
China Agricultural University Department of Applied Chemistry, College of Science Beijing 100193 China,
Pan, C.
China Agricultural University Department of Applied Chemistry, College of Science Beijing 100193 China,
Sheikhloie, H.
slamic Azad University, Science and Research Branch Department of Chemistry, Faculty of Science Poonak-Hesarak, Tehran Iran,
Saber-Tehrani, M.
slamic Azad University, Science and Research Branch Department of Chemistry, Faculty of Science Poonak-Hesarak, Tehran Iran,
Abrumand-Azar, P.
slamic Azad University, Science and Research Branch Department of Chemistry, Faculty of Science Poonak-Hesarak, Tehran Iran,
Waqif-Husain, S.
slamic Azad University, Science and Research Branch Department of Chemistry, Faculty of Science Poonak-Hesarak, Tehran Iran,
Mincea, M.
West University of Timişoara Faculty of Chemistry-Biology-Geography, Department of Chemistry Pestalozzi Street, 16 Timişoara 300115 Romania,
Lupşa, I.
Institute of Public Health Timişoara Department of Food Hygiene V. Babeş 16-18 Timişoara 300226 Romania,
Talpoş, I.
West University of Timişoara Multidisciplinary Research Platform “Nicholas Georgescu-Roegen” Oituz 4 Timişoara Romania,
Ostafe, V.
West University of Timişoara Faculty of Chemistry-Biology-Geography, Department of Chemistry Pestalozzi Street, 16 Timişoara 300115 Romania, vostafe@cbg.uvt.ro,
Milenović, D. M.
Zdravlje-Actavis Company, R&D Analytical Department 16000 Leskovac Serbia, dmilenovic@actavis.rs,
Todorović, Z. B.
University of Niš Faculty of Technology 16000 Leskovac Serbia,
Rane, V. P.
Dr Babasaheb Ambedkar Marathwada University Department of Chemical Technology Aurangabad 431004 (MS) India,
Patil, K. R.
Dr Babasaheb Ambedkar Marathwada University Department of Chemical Technology Aurangabad 431004 (MS) India,
Sangshetti, J. N.
Wockhardt Research Centre Aurangabad 431210 (MS) India,
Yeole, R. D.
Wockhardt Research Centre Aurangabad 431210 (MS) India,
Shinde, D. B.
Dr Babasaheb Ambedkar Marathwada University Department of Chemical Technology Aurangabad 431004 (MS) India,
Ahmad, S.
Hamdard University Department of Pharmaceutics, Faculty of Pharmacy Hamdard Nagar New Delhi 110062 India,
Jain, G. K.
Hamdard University Department of Pharmaceutics, Faculty of Pharmacy Hamdard Nagar New Delhi 110062 India,
Faiyazuddin, M.
Hamdard University Department of Pharmaceutics, Faculty of Pharmacy Hamdard Nagar New Delhi 110062 India,
Iqbal, Z.
Hamdard University Department of Pharmaceutics, Faculty of Pharmacy Hamdard Nagar New Delhi 110062 India,
Talegaonkar, S.
Hamdard University Department of Pharmaceutics, Faculty of Pharmacy Hamdard Nagar New Delhi 110062 India,
Sultana, Y.
Hamdard University Department of Pharmaceutics, Faculty of Pharmacy Hamdard Nagar New Delhi 110062 India,
Ahmad , F. J.
Hamdard University Department of Pharmaceutics, Faculty of Pharmacy Hamdard Nagar New Delhi 110062 India,
Cieśla, Ł.
Medical University of Lublin Department of Inorganic Chemistry 6 Staszica Street 20-081 Lublin Poland,
Skalicka-Woźniak, K.
Medical University of Lublin Department of Pharmacognosy 1 Chodźki Street 20-093 Lublin Poland,
Hajnos, M.
Medical University of Lublin Department of Pharmacognosy 1 Chodźki Street 20-093 Lublin Poland,
Hawrył, M.
Medical University of Lublin Department of Inorganic Chemistry 6 Staszica Street 20-081 Lublin Poland,
Waksmundzka-Hajnos, M.
Medical University of Lublin Department of Inorganic Chemistry 6 Staszica Street 20-081 Lublin Poland,
Abstrakty : Identification of closely related plant species is not a trivial task, and is often difficult on the basis of morphological or anatomical features. To differentiate among analyzed species, a chromatographic fingerprint is usually constructed. This is not easy for very complex samples, however, especially those containing substances spanning a wide polarity range. In such circumstances more than one fingerprint is constructed, e.g. one for polar and the other for apolar constituents. In this paper a new method has been used for resolution of a mixture of 17 coumarins and flavonoids and, subsequently, construction of a fingerprint of closely related species belonging to the Peucedanum genus. This is the first time multidimensional planar chromatography has been applied for such purpose. Distinctive fingerprints are produced for every analyzed plant species, without the need to construct two fingerprints and without the application of more sophisticated multidimensional methods (e.g. hyphenation of HPLC and TLC, HPLC-MS, etc).

Słowa kluczowe : multidimensional planar chromatography, multicomponent mixtures, fingerprint construction, Peucedanum,
Wydawnictwo : University of Silesia in Katowice
Rocznik : 2009
Numer : Vol. 21, no. 4
Strony : 641 – 657
Bibliografia : 1 X.H. Fan, Z.L. Cheng, Z.L. Ye, R.Ch. Lin, and Z.Z. Qian, Anal. Chim. Acta, 555 , 217–224 (2006)
2 M. Obradovič, S. Strgulc Krajšek, M. Dermastia, and S. Kreft, Phytochem. Anal., 18 , 123–132 (2007)
3 E. Reich and A. Schibli, High-Performance Thin-layer Chromatography for the Analysis of Medicinal Plants, Thieme, New York, 2006
4 Ł. Cieśla, A. Bogucka-Kocka, M. Hajnos, A. Petruczynik, and M. Waksmundzka-Hajnos, J. Chromatogr. A, 1207 , 160–168 (2008)
5 L. Zhang, R.W. Zhang, L. Qing, J.W. Lian, J. Liang, X.H. Chen, and K.S. Bi, Chromatographia 66 , 13–20 (2007)
6 Ł. Cieśla and M. Waksmundzka-Hajnos, J. Chromatogr. A, 1216 , 1035–1052 (2009)
7 A. Petruczynik, M. Waksmundzka-Hajnos, T. Michniowski, T. Plech, T. Tuzimski, M.Ł. Hajnos, M. Gadzikowska, and G. Jóźwiak, J. Chromatogr. Sci., 45 , 447–454 (2007)
8 M. Waksmundzka-Hajnos, A. Petruczynik, M.Ł. Hajnos, T. Tuzimski, A. Hawrył, and A. Bogucka-Kocka, J. Chromatogr. Sci., 44 , 510–517 (2006)
9 M.A. Hawrył, A. Hawrył, and E. Soczewiński, J. Planar Chromatogr., 15 , 4–10 (2002)
10 A. Petruczynik, M. Waksmundzka-Hajnos, T. Plech, T. Tuzimski, M.Ł. Hajnos, G. Jóźwiak, M. Gadzikowska, and A. Rompała, J. Chromatogr. Sci., 46 , 291–297 (2008)
11 M. Łuczkiewicz, P. Migas, A. Kokotkiewicz, M. Walijewska, and W. Cisowski, J. Planar Chromatogr., 17 , 89–94 (2004)
12 M. Glensk, U. Sawicka, I. Mażol, and W. Cisowski, J. Planar Chromatogr., 15 , 463–465 (2002)
13 G. Matysik, A. Skalska-Kamińska, B. Stefańczyk, M. Wójciak-Kosior, and D. Rapa, J. Planar Chromatogr., 21 , 233–236 (2008)
14 M.A. Hawrył, E. Soczewiński, and T.H. Dzido, J. Chromatogr. A, 886 , 75–81 (2000)
15 T. Tuzimski, J. Sep. Sci., 31 , 3537–3542 (2007)
16 V.S. Shneyer, N.G. Kutyavina, and M.G. Pimenov, Plant Syst. Evol., 236 , 175–194 (2003)
17 A. Bogucka-Kocka and T. Krzaczek, Acta Pol. Pharm., 60 , 391–393 (2003)
DOI :
Cytuj : Daszykowski, M. ,Sajewicz, M. ,Rzepa, J. ,Hajnos, M. ,Staszek, D. ,Wojtal, Ł. ,Kowalska, T. ,Waksmundzka-Hajnos, M. ,Walczak, B. ,Skalicka-Woźniak, K. ,Markowski, W. ,Świeboda, R. ,Głowniak, K. ,Sultana, N. ,Arayne, M. S. ,Naveed, S. ,Shamshad, H. ,Li, X. ,Xu, J. ,Jiang, Y. ,Chen, L. ,Xu, Y. ,Pan, C. ,Sheikhloie, H. ,Saber-Tehrani, M. ,Abrumand-Azar, P. ,Waqif-Husain, S. ,Mincea, M. ,Lupşa, I. ,Talpoş, I. ,Ostafe, V. ,Milenović, D. M. ,Todorović, Z. B. ,Rane, V. P. ,Patil, K. R. ,Sangshetti, J. N. ,Yeole, R. D. ,Shinde, D. B. ,Ahmad, S. ,Jain, G. K. ,Faiyazuddin, M. ,Iqbal, Z. ,Talegaonkar, S. ,Sultana, Y. ,Ahmad , F. J. ,Cieśla, Ł. ,Skalicka-Woźniak, K. ,Hajnos, M. ,Hawrył, M. ,Waksmundzka-Hajnos, M. , Multidimensional TLC procedure for separation of complex natural mixtures spanning a wide polarity range; Application for fingerprint construction and for investigation of systematic relationships within the Peucedanum genus. Acta Chromatographica Vol. 21, no. 4/2009
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