Journal : Acta Chromatographica
Article : Quaternary separation of some transition metal chlorosulphates on mixed adsorbent layers with water as mobile phase. Quantitative determination of nickel chlorosulphate

Authors :
Kowalska, T.
Institute of Chemistry, Silesian University, 9 Szkolna Street, 40-006 Katowice, Poland,
Kaczmarski, K.
Chemical Engineering Department, Rzeszów University of Technology, Rzeszów, Poland,
Pavlova, A.
Analytical Department, Research and Development Institute, Lukoil-Neftochim-Bourgas-AD, 8104 Bourgas, Bulgaria,
Giza, I.
Plant Protection Institute, Sośnicowice Branch, ul. Gliwicka 29, 44-153 Sośnicowice, Poland,
Walorczyk, S.
Institute of Plant Protection, Department of Pesticide Residue Research, ul. Miczurina 20, 60-318 Poznań, Poland,
Waksmundzka-Hajnos, M.
Department of Inorganic and Analytical Chemistry, Medical University, Staszica 6, 20-081 Lublin, Poland,
Gadzikowska, M.
Department of Inorganic and Analytical Chemistry, Medical Academy, Staszica 6, 20-081 Lublin, Poland,
Nagahashi, M.
Laboratory of Instrumental Analysis, Tokyo University of Agriculture, 1-1, Sakuragaoka-1, Setagaya, Tokyo 156-8502, Japan,
Fisher, J.
Department of Chemistry, Lafayette College, Easton, PA 18042, USA,
Schariter, J. J.
Department of Chemistry, Lafayette College, Easton, PA 18042, USA,
Bodzek, D.
Department of Chemistry, Faculty of Medicine, Medical University of Silesia, 41-808 Zabrze, Jordana 19, Poland,
Nabi, S. A.
Analytical Research Laboratory, Department of Chemistry, Aligarh Muslim University, Aligarh-202002, India,
Nabi, S. A.
Analytical Research Laboratory, Department of Chemistry, Aligarh Muslim University, Aligarh-202002, India,
Misra, A. K.
Department of Chemistry, NNISN Dass (PG) College, Budaun 243 601 (UP), India,
Mohammad, A.
Analytical Research Laboratory, Department of Applied Chemistry, Z.H. College of Engineering and Technology, Aligarh Muslim University, Aligarh-202002, India,
Abstract : The analytical potential of double-distilled water for the separation of transition metal chlorosulphates is described. Nickel chlorosulphate is well separated from manganese, iron, copper, or zinc chlorosulphates on mixed silica gel-cellulose (2:1 w/w) adsorbent layers. Several stationary phase-mobile phase combinations were tested to identify suitable chromato-graphic systems for analysis of metal chlorosulphates. Quaternary separations, e.g. Mn-Fe-Ni-Cu and Mn-Fe-Ni-Zn have been achieved. The effect of anionic species on the mobility and separation of metal chlorosulphates has been examined. Nickel as its chlorosulphate has been quantitatively determined after TLC separation from Mn, Fe, and Zn chlorosulphates on mixed silica gel-cellulose layers with double-distilled water as mobile phase.

Keywords :
Publishing house : University of Silesia in Katowice
Publication date : 2001
Number : No. 11
Page : 154 – 170

Bibliography
:
DOI :
Qute : Kowalska, T. ,Kaczmarski, K. ,Pavlova, A. ,Giza, I. ,Walorczyk, S. ,Waksmundzka-Hajnos, M. ,Gadzikowska, M. ,Nagahashi, M. ,Fisher, J. ,Schariter, J. J. ,Bodzek, D. ,Nabi, S. A. ,Nabi, S. A. ,Misra, A. K. ,Mohammad, A. ,Mohammad, A. , Quaternary separation of some transition metal chlorosulphates on mixed adsorbent layers with water as mobile phase. Quantitative determination of nickel chlorosulphate. Acta Chromatographica No. 11/2001
facebook