Journal : Acta Chromatographica
Article : Thin layer chromatography of inorganic ions on blended inorganic ion-exchangers with tributyl phosphate-formic acid as mobile phase

Authors :
Kowalska, T.
Institute of Chemistry, Silesian University, 9 Szkolna Street, 40-006 Katowice, Poland,
Kaczmarski, K.
Chemical Engineering Department, Rzeszów University of Technology, Rzeszów, Poland,
Pavlova, A.
Analytical Department, Research and Development Institute, Lukoil-Neftochim-Bourgas-AD, 8104 Bourgas, Bulgaria,
Giza, I.
Plant Protection Institute, Sośnicowice Branch, ul. Gliwicka 29, 44-153 Sośnicowice, Poland,
Walorczyk, S.
Institute of Plant Protection, Department of Pesticide Residue Research, ul. Miczurina 20, 60-318 Poznań, Poland,
Waksmundzka-Hajnos, M.
Department of Inorganic and Analytical Chemistry, Medical University, Staszica 6, 20-081 Lublin, Poland,
Gadzikowska, M.
Department of Inorganic and Analytical Chemistry, Medical Academy, Staszica 6, 20-081 Lublin, Poland,
Nagahashi, M.
Laboratory of Instrumental Analysis, Tokyo University of Agriculture, 1-1, Sakuragaoka-1, Setagaya, Tokyo 156-8502, Japan,
Fisher, J.
Department of Chemistry, Lafayette College, Easton, PA 18042, USA,
Schariter, J. J.
Department of Chemistry, Lafayette College, Easton, PA 18042, USA,
Bodzek, D.
Department of Chemistry, Faculty of Medicine, Medical University of Silesia, 41-808 Zabrze, Jordana 19, Poland,
Nabi, S. A.
Analytical Research Laboratory, Department of Chemistry, Aligarh Muslim University, Aligarh-202002, India,
Nabi, S. A.
Analytical Research Laboratory, Department of Chemistry, Aligarh Muslim University, Aligarh-202002, India,
Misra, A. K.
Department of Chemistry, NNISN Dass (PG) College, Budaun 243 601 (UP), India,
Mohammad, A.
Analytical Research Laboratory, Department of Applied Chemistry, Z.H. College of Engineering and Technology, Aligarh Muslim University, Aligarh-202002, India,
Mohammad, A.
Analytical Research Laboratory, Department of Applied Chemistry, Faculty of Engineering and Technology, AMU, Aligarh-202002, India,
Abstract : The chromatographic behaviour of some cations and anions has been examined on layers prepared from 1:9 mixtures of a synthetic inorganic ion-exchanger (stannic arsenate or tin(IV) molybdosilicate, synthesized under different experimental conditions) with silica gel, alumina, or cellulose, with tri-n-butyl phosphate-formic acid as mobile phase. Several binary separations of analytical interest were achieved on these blended adsorbent phases. The effect of pH on the separation of IO3- from NO2- and BrO3- in the presence of cations was also examined. Quantitative determination of IO3- on mixed stannic arsenate-alumina, 1:9, was also performed success-fully.

Keywords :
Publishing house : University of Silesia in Katowice
Publication date : 2001
Number : No. 11
Page : 171 – 182

Bibliography
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DOI :
Qute : Kowalska, T. ,Kaczmarski, K. ,Pavlova, A. ,Giza, I. ,Walorczyk, S. ,Waksmundzka-Hajnos, M. ,Gadzikowska, M. ,Nagahashi, M. ,Fisher, J. ,Schariter, J. J. ,Bodzek, D. ,Nabi, S. A. ,Nabi, S. A. ,Misra, A. K. ,Mohammad, A. ,Mohammad, A. ,Mohammad, A. , Thin layer chromatography of inorganic ions on blended inorganic ion-exchangers with tributyl phosphate-formic acid as mobile phase. Acta Chromatographica No. 11/2001
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